- by Lam Kim HuynhThe detailed kinetic mechanism between isobutene and SiH3 radicals was investigated theoretically using the composite electronic structure method CBS-QB3 in conjugated with the Rice-Ramsperger-Kassel-Marcus-based master equation (RRKM-ME) rate modeling. The study reveals that the title reaction proceeds through two primary pathways: (i) addition of SiH3 to the double bond and (ii) H-abstraction by SiH3, leading […]
